Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献   

An immersed boundary method for compressible multiphase flows: application to the dynamics of pyroclastic density currents     

Mattia de’ Michieli Vitturi  Tomaso Esposti Ongaro  Augusto Neri  Maria Vittoria Salvetti  François Beux 《Computational Geosciences》2007,11(3):183-198

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Determination of source and palaeoclimate from the comparison of grain and clay fractions in sandstones: A case study     

Gürol Ataman  Sungu L. Gökçen 《Sedimentary Geology》1975,13(2):81-107

The Paleogene Ke?an Formation of southwestern Turkish Thrace (Alpine Ergene basin) which is dominantly a sandy facies, comprises the Çinarlidere (Lower) and ?aplidere (Upper) members. The turbidite sandstones of the Formation are petrologically defined as multicycle, moderately sorted, angular to subrounded, coarse-skewed, submature graywackes with a detrital clayey matrix of over 15%.The quantitative analyses of light, heavy and clay fractions of sandstone samples from the Ke?an Formation showed marked petrographic variations with grouping of these sediments as Lower- and Upper-member mineralogical facies and led to the following conclusions: a southern terrain with a relatively warm and tropical climate on a terrestrial source of a peneplain topography provided detrital material for the Lower-member sediments (the Biga Massif), while the Upper-member sediments were derived from a rapid erosion of an area of high relief with a uniform supply and continuous infilling of the basin of deposition (a western source terrain: the Rhodope Massif).  相似文献   

Relations entre les données isotopiques océaniques et l'histoire des grandes faunes européennes plio-pleistocenes     

Marie-Françoise Bonifay 《Quaternary Research》1980,14(2):251-262

This study is the first test of correlation between the results obtained on the large Plio-Pleistocene European faunas and the main climatic stages (cold as well as temperate) demonstrated in marine isotopic records. In particular, there are cold stages which often explain the disappearance of some species, as well as climatic events that promote the substitution of some species by other groups. A rather evident parallelism appears between the European succession of large faunal associations and paleoclimatic stages revealed in oceanic areas, but some discordance occurs in the later periods. Faced with the great diversification of the Quaternary faunas, probably due to the multiplicity of climatic environments, and with global information from oceanic records, only local biostratigraphic studies will allow precise reconstruction of the different biotopes.  相似文献   

Twenty Years Seismic Monitoring of Induced Seismicity in Northern Albania     

B. Muço 《Pure and Applied Geophysics》1998,153(1):151-162

—The northern part of Albania has been the focus of an intense effort by the Seismological Institute of Albania, for in this area two of the country’s biggest reservoirs are located. Three years before the impounding of the Fierza reservoir, a four-station network was installed around it. The possibility of induced seismicity continued after the impoundment of the Fierza reservoir in 1978 and the Komani reservoir, in 1985. The seismicity of the zone and some aspects of induced seismicity including temporal correlation of seismicity with water level changes, spatial patterns in seismicity, frequency-mag nitude relations, fault plane solutions etc., are studied during this period. The presence in this zone of a very important transverse fault, the Shkoder-Peja fault, makes the study of induced seismicity from Fierza and Komani reservoirs even more significant. The studies have shown that the impounding of the Fierza and Komani reservoirs has modified the natural course of microearthquake energy release, increasing the number of swarms in this area.¶The fluctuation of the water level in these two reservoirs, in due course, is a potentially important factor in the evaluation of seismicity for Northern Albania and especially in the hazard assessment of this region.  相似文献   

Production of radionuclides by cosmic rays at mountain altitudes     

Yuji Yokoyama  Jean-Louis Reyss  François Guichard 《Earth and Planetary Science Letters》1977,36(1):44-50

Production rates of²²Na (T_1/2 = 2.6years) from aluminium by the action of cosmic rays are measured at the Mont Blanc (altitude 4600 m), the Aiguille du Midi (3840 m), and the Col du Lautaret (2070 m). They are2.3 ± 0.5,1.8 ± 0.3,and0.77 ± 0.18 atoms min^?1 kg^?1, respectively, in good agreement with the calculated production rates, 2.4, 1.7 and 0.6 atoms min^?1 kg^?1, respectively, at the three stations.Production rates of²⁴Na (T_1/2 = 15hours) from aluminium and magnesium are also measured at the Aiguille du Midi; the observed rates of3.4 ± 0.4and6.0 ± 1.7 atoms min^?1 kg^?1, respectively, agree well with the theoretically expected rates of 3.7 and 5.6 atoms min^?1 kg^?1.The production rates of³H,⁷Be,¹⁰Be,¹⁴C,²²Na,²⁶Al,³⁶Cl,³⁷Ar,³⁹Ar,⁵³Mn,⁵⁴Mn, and⁵⁵Fe in terrestrial rocks by the action of cosmic rays are calculated in order to show the possibility of applying the measurements of these cosmogenic radionuclides to the earth science.  相似文献   

ACMEG‐TS: A constitutive model for unsaturated soils under non‐isothermal conditions     

Bertrand François  Lyesse Laloui 《国际地质力学数值与分析法杂志》2008,32(16):1955-1988

This paper introduces an unconventional constitutive model for soils, which deals with a unified thermo‐mechanical modelling for unsaturated soils. The relevant temperature and suction effects are studied in light of elasto‐plasticity. A generalized effective stress framework is adopted, which includes a number of intrinsic thermo‐hydro‐mechanical connections, to represent the stress state in the soil. Two coupled constitutive aspects are used to fully describe the non‐isothermal behaviour. The mechanical constitutive part is built on the concepts of bounding surface theory and multi‐mechanism plasticity, whereas water retention characteristics are described using elasto‐plasticity to reproduce the hysteretic response and the effect of temperature and dry density on retention properties. The theoretical formulation is supported by comparisons with experimental results on two compacted clays. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Nature and role of CO2 in some hot and cold HCO3/Na/CO2-rich Portuguese mineral waters: a review and reinterpretation     

José M. Marques  Paula M. M. Carreira  Luís Aires-Barros  Rui C. Graça 《Environmental Geology》2000,40(1-2):53-63

 At the northern part of the Portuguese mainland, the upflow zone of several hot and cold HCO₃/Na/CO₂-rich mineral waters is mainly associated with important NNE–SSW faults. Several geochemical studies have been carried out on thermal and non-thermal hydromineral manifestations that occur along or near these long tectonic alignments. The slight chemical differences that exist between these meteoric hot and cold HCO₃/Na/CO₂-rich mineral waters seem to be mainly caused by CO₂. δ¹³C_(TIDC) values observed in these groundwaters range between –6.00 and –1.00‰ versus V-PDB (V denotes Vienna, the site of the International Atomic Energy Agency; PDB originates from the CaCO₃ of the rostrum of a Cretaceous belemnite, Belemnitella americana, collected in the Peedee formation of South Carolina, USA) indicating a deep-seated (mantle) origin for most of the CO₂. Nevertheless, in the case of the heavier δ¹³C_(TIDC) values, the contribution of metamorphic CO₂ or the dissolution of carbonate rock levels at depth cannot be excluded. Concerning the hot waters, the lack of a positive ¹⁸O-shift should be attributed to water-rock interaction in a low temperature environment, rather than to the isotopic influence of CO₂ on the δ¹⁸O-value of the waters. Received: 9 August 1999 · Accepted: 8 March 2000  相似文献   

Origin of Early Carboniferous pseudo‐adakites in northern Brittany (France) through massive amphibole fractionation from hydrous basalt     

Mélanie Barboni  François Bussy  Massimo Chiaradia 《地学学报》2011,23(1):1-10

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Multiscale approach to geo‐composite cellular structures subjected to rock impacts     

François Nicot  Philippe Gotteland  David Bertrand  Stéphane Lambert 《国际地质力学数值与分析法杂志》2007,31(13):1477-1515

Geo‐composite cellular structures are an efficient technological solution for various applications in civil engineering. This type of structure is particularly well adapted to resisting rockfalls and can act as a defensive structure. However, the design of such structures is for the most part empirically based; this lack of research‐based design stagnates optimization and advanced development. In this paper, the mechanical behaviour of a geo‐composite cellular structure is investigated using a multi‐scale approach, from the individual cell made up of an assembly of rocky particles contained in a wire netting cage to the entire structure composed of a regular array of cells. Based on discrete modelling of both the cell and structure scales, a computational tool has been developed for design purposes. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献